Linalool je prirodni terpenski alkohol koji je prisutan u mnogim cvetajucim i zacinskim biljkama. On ima mnostvo komercijalnih primena, vecina kojih se bazira na prijatnom mirisu. Njegova druga imena su: b-linalool, linalil alkohol, linaloil oksid, p-linalool, alo-ocimenol, i 2,6-dimetil-2,7-oktadien-6-ol.

Priroda

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Preko 200 biljnih vrsta proizvodi linalool. One su uglavnom iz porodica Lamiaceae (menta, mirisljave trave), Lauraceae (lavor, cimet, palisandrovo drvo), i Rutaceae (citrusno voce).

Enantiomeri

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Linalool ima stereogeni centar na C₃ i stoga postoje dva stereoizomera: (R)-(-)-linalool je takode poznat kao likareol i (S)-(+)-linalool ili koriandrol.

(S)-(+)-linalool (levo) i (R)-(-)-linalool (desno)

Literatura

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Casabianca H, Graff JB, Faugier V, Fleig F, Grenier C (1998) Enantiomeric distribution studies of linalool and linalyl acetate. A powerful tool for authenticity control of essential oils. HRC J High Res Chrom 21:107-112
Lewinshon E, Schalechet F, Wilkinson J, Matsui K, Tadmor Y, Nam K, Amar O, Lastochkin E, Larkov O, Ravid U, Hiatt W, Gepstein S, Pichersky E (2001) Enhanced levels of the aroma and flavor compound S-linalool by metabolic engineering of the terpenoid pathway in tomato fruits. Plant Physiol 127:1256-1265
Pengelly, Andrew. The Constituents of Medicinal Plants. 2nd Ed. 2004. CABI Publishing, U.S.A. and UK.
Raguso RA, Pichersky E (1999) A day in the life of a linalool molecule: chemical communication in a plant-pollinator system. Part 1: linalool biosynthesis in flowering plants. Plant Species Biol 14:95-120
Akio Nakamura, Satoshi Fujiwara, Ichiro Matsumoto and Keiko Abe. Stress Repression in Restrained Rats by (R)-(-)-Linalool Inhalation and Gene Expression Profiling of Their Whole Blood Cells. J. Agric. Food Chem., 2009, 57 (12), pp 5480-5485.

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Reference

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